Fabrication and characterization of nanostructured titanate materials by the hydrothermal treatment method

Doong, Ruey-An (Department of Biomedical Engineering and Environmental Sciences, National Tsing Hua University); Kao, I.-Ling

Source: Recent Patents on Nanotechnology, v 2, n 2, June, 2008, p 84-102

ISSN: 1872-2105

Publisher: Bentham Science Publishers B.V.

Abstract: The synthesis and characterization of one-dimensional (1-D) tubular and fibrous nanostructured materials have recently received highly attention. Various morphologies of 1-D nanostructured titanate materials including nanosheets, nanotubes, nanowires, and nanoribbons have recently been successfully synthesized using the alkaline hydrothermal method. In spite of the controversy of the chemical structures and formation mechanisms, titanate nanostructures have attracted much attention on applications of dye-sensitized solar cell, hydrogen sensing, lithium storage and photocatalysis because of their unique features of high specific surface area, ion-exchange capacity and aspect ratio, and unique optical and electrochemical properties. The morphology and microstructure of titanate nanostructures are highly dependent on the preparation conditions. In this review, we highlight the synthesis of TiO₂-derived nanomaterials under various hydrothermal conditions. The patents for fabrication of various morphologies of nanostructures are also introduced Effects of preparation parameters including hydrothermal temperature, duration, alkaline concentration, starting materials, and post-treatment on the morphology and microstructure of titanate nanomaterials are reviewered. In addition, the microwave-assisted method for fabrication of 1-D titanate nanostructures is discussed and compared. The applications of titanate nanomaterials in photocatalysis, ion-exchange, and lithium storages are also introduced. © 2008 Bentham Science Publishers Ltd. (140 refs.)

 terms:  Nanostructured materials  -  Aspect ratio  -  Catalysis  -  Chemical properties  -  Concentration (process)  -  Data storage equipment  -  Electric wire  -  Electrochemical properties  -  Fabrication  -  Hydrogen storage  -  Hydrogen  -  Ion exchange  -  Ion exchangers  -  Lithium  -  Microstructure  -  Microwaves  -  Morphology  -  Nanostructures  -  Nanotubes  -  Photocatalysis  -  Solar cells  -  Solar energy  -  Solar power generation  -  Storage (materials)  -  Titanium dioxide  -  Titanium